On the structural features of iron-phosphate glasses by Raman and EPR: Observation of superparamagnetic behavior differences in HfO2 or CeO2 containing glasses
Yazarlar (7)
M. Karabulut
Gebze Teknik Üniversitesi, Türkiye
A. Popa
National Institute For Research And Development Of Isotopic And Molecular Technologies, Romanya
C. Berghian-Grosan
National Institute For Research And Development Of Isotopic And Molecular Technologies, Romanya
Prof. Dr. Hüseyin ERTAP
Kafkas Üniversitesi, Türkiye
M. Yüksek
Kafkas Üniversitesi, Türkiye
S. Tokdemir Öztürk
Gebze Teknik Üniversitesi, Türkiye
R. Stefan
Universitatea De Stiinte Agricole Si Medicina Veterinara Din Cluj-Napoca, Romanya
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2019 |
| Cilt / Sayı / Sayfa | 1191 / 1 / 59–65 | DOI | 10.1016/j.molstruc.2019.04.086 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0022286019304892 | ||
| Özet |
| Structural features of hafnium or cerium doped iron borophosphate glasses have been studied by Raman and EPR spectroscopies. Hf and Ce are introduced into the composition as surrogates for Pu. Raman spectrum of Hf and Ce free base iron phosphate glass indicate that the glass network consisted mainly of Q1 units with contributions from Q2 units. The general features observed for base glass are maintained in the Raman spectra of Hf/Ce containing glasses with some modifications with increasing Ce/Hf content in the composition. The EPR spectra of Hf and Ce containing glasses show different features. Superparamagnetic domains were highlighted through EPR for all CeO2 containing glasses. |
| Anahtar Kelimeler |
| Iron phosphate glasses | Raman | EPR | Waste immobilization |