Polaronic transport in iron phosphate glasses containing HfO2 and CeO2
Yazarlar (7)
Ana Santic Institut Ruđer Bošković, Hırvatistan
Radha D Banhatti Institut Ruđer Bošković, Hırvatistan
Luka Pavic Institut Ruđer Bošković, Hırvatistan
Prof. Dr. Hüseyin ERTAP Kafkas Üniversitesi, Türkiye
Mustafa Yüksek Kafkas Üniversitesi, Türkiye
Mevlüt Karabulut Gebze Teknik Üniversitesi, Türkiye
Andrea Mogus Milankovic Institut Ruđer Bošković, Hırvatistan
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Physical Chemistry Chemical Physics (Q2) | ||
| Dergi ISSN | 1463-9076 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2017 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2017 |
| Cilt / Sayı / Sayfa | 19 / 5 / 3999–4009 | DOI | 10.1039/C6CP04226K |
| Makale Linki | http://dx.doi.org/10.1039/c6cp04226k | ||
| Özet |
| The electrical and dielectric properties of three series of glasses, xHfO2–(40 − x)Fe2O3–60P2O5, 0 ≤ x ≤ 8 mol%, xCeO2–(40 − x)Fe2O3–60P2O5, 0 ≤ x ≤ 8 mol%, and xHfO2–(38 − x)Fe2O3–2B2O3–60P2O5 2 ≤ x ≤ 6 mol%, have been investigated by impedance spectroscopy over a wide frequency and temperature range. As expected, these glasses exhibit polaronic conductivity which strongly depends on the fraction of ferrous ions, Fe2+/Fetot. Following a detailed discussion on the DC conductivity, we use the MIGRATION concept to model their conductivity spectra. It is found that in each series of glasses, the shape of the conductivity isotherms remains the same indicating that the time-temperature superposition principle is satisfied and that the mechanism of conductivity is the same. Returning to a model-free scaling procedure, namely Summerfield scaling, it is found that while conductivity isotherms for … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
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| Google Scholar | 32 |
| Web of Science | 24 |
| Scopus | 25 |