Synthesis of poly epichlorohydrin g methyl methacrylate and poly epichlorohydrin g styrene graft copolymers by a combination of cationic and photopolymerization methods
Yazarlar (3)
Prof. Dr. İsmail ÇAKMAK Kafkas Üniversitesi, Türkiye
Haci Baykara
Siirt Üniversitesi, Türkiye
Siirt Üniversitesi, Türkiye
Set Barış
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | JOURNAL OF APPLIED POLYMER SCIENCE | ||
| Dergi ISSN | 0021-8995 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2008 |
| Kabul Tarihi | 14-04-2026 | Yayınlanma Tarihi | – |
| Cilt / Sayı / Sayfa | 107 / 107 / 1604–1608 | DOI | 10.1002/app.27217 |
| Özet |
| AbstractPoly(epichlorohydrin‐g‐styrene) and poly (epichlorohydrin‐g‐methyl methacrylate) graft copolymers were synthesized by a combination of cationic and photoinitiated free‐radical polymerization. For this purpose, first, epichlorohydrin was polymerized with tetrafluoroboric acid (HBF4) via a cationic ring‐opening mechanism, and, then, polyepichlorohydrin (PECH) was reacted ethyl‐hydroxymethyl dithio sodium carbamate to obtain a macrophotoinitiator. PECH, possessing photolabile thiuram disulfide groups, was used in the photoinduced polymerization of styrene or methyl methacrylate to yield the graft copolymers. The graft copolymers were characterized by 1H‐NMR spectroscopy, differential scanning calorimetry, and gel permeation chromatography. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 |
| Anahtar Kelimeler |
| graft copolymers | photopolymerization | cationic polymerization | macrophotoinitiator |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 5 |