Molecular Imprinted Sensor Including Au Nanoparticles/Polyoxometalate/Two-Dimensional Hexagonal Boron Nitride Nanocomposite for Diazinon Recognition
   
Yazarlar (10)
Doç. Dr. Hilal MEDETALİBEYOĞLU Kafkas Üniversitesi, Türkiye
Doç. Dr. Murat BEYTUR Kafkas Üniversitesi, Türkiye
Doç. Dr. Sevda MANAP Kafkas Üniversitesi, Türkiye
Ceren Karaman Akdeniz Üniversitesi, Türkiye
Faruk Kardaş Erzincan Binali Yıldırım Üniversitesi, Türkiye
Doç. Dr. Onur AKYILDIRIM Kafkas Üniversitesi, Türkiye
Doç. Dr. Gül KOTAN Kafkas Üniversitesi, Türkiye
Prof. Dr. Haydar YÜKSEK Kafkas Üniversitesi, Türkiye
Mehmet Lütfi Yola Iskenderun Technical University, Türkiye
Necip Atar Pamukkale Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Ecs Journal of Solid State Science and Technology
Dergi ISSN 2162-8769 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 10-2020
Cilt / Sayı / Sayfa 9 / 10 / 101006–0 DOI 10.1149/2162-8777/abbe6a
Özet
Diazinon [O,O-diethyl O-(2-isopropyl-6-methylpyrimidin4-yl) thiophosphate] (DIA) is a significant organophosphorus insecticide in agricultural applications. Thus, sensitive analytical methods development is important for a healthy lifestyle. In this work, the electrochemical detection of DIA molecule in fruit juice samples by using gold nanoparticles (AuNPs) incorporated polyoxometalate (POM)/two-dimensional hexagonal boron nitride (2D-hBN) nanosheets and molecularly imprinted polymer (MIP) was reported. To characterize as-prepared nanomaterials scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and energy dispersive X-ray analysis (EDX) techniques were performed. The electrochemical behavior of the electrodes was examined by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and differential pulse voltammetry (DPV). The as-fabricated DIA imprinted electrode displayed a wide linear range and highly sensitive response to DIA. Moreover, the detection limit (LOD) found to be 3.0 10-12 M. The modified sensor.was successfully used for recognition of DIA in fruit juices.
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