Synthesis of benzidine-based conjugated organic materials bearing donor-acceptor groups: DFT studies and photovoltaic applications
Yazarlar (4)
Doç. Dr. Ali YEŞİLDAĞ Kafkas Üniversitesi, Türkiye
Doç. Dr. Musa ERDOĞAN Kafkas Üniversitesi, Türkiye
Doç. Dr. Hilal MEDETALİBEYOĞLU Kafkas Üniversitesi, Türkiye
Sabit Horoz Siirt Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2022 |
| Cilt / Sayı / Sayfa | 1251 / 1 / – | DOI | 10.1016/j.molstruc.2021.131939 |
| Makale Linki | http://dx.doi.org/10.1016/j.molstruc.2021.131939 | ||
| Özet |
| Herein, tetraethoxymethyl, diphenyl, and dipyrenyl units have been fused with biphenyl group, via diimine bond, resulting in 3 (2 novel) benzidine derivatives 2, 4a-b. The derivatives were successfully synthesized by condensation of three different aldehydes (formaldehyde, benzaldehyde 3a, and pyrenecarboxaldehyde 3b) with benzidine in high yields. Structural identifications of the newly obtained compounds are determined by NMR, IR, UV–Vis, and HRMS spectroscopic techniques. Then, the photovoltaic properties of the organic compounds were investigated. To obtain insight into the geometric, electronic, and spectroscopic features of compounds 2, 4a-b, theoretical calculations were performed utilizing the B3LYP/6–311G(2d,2p) basis set. Theoretical 1H and 13C NMR resonance signals of compounds 2, 4a-b were estimated in the gas phase and the IEFPCM model in solvent field calculations utilizing the … |
| Anahtar Kelimeler |
| Benzidine | DFT | DSSC | Photovoltaic | Power conversion efficiency | Pyrene |
Science Direct
Synthesis of benzidine-based conjugated organic materials bearing donor-acceptor groups: DFT studies and photovoltaic applications
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 14 |
| Google Scholar | 15 |