A novel fluorinated monomer: Synthesis, characterization and ATRP of 5,6,7,8-tetrafluoronaphthalen-1-yl acrylate
Yazarlar (3)
Doç. Dr. Musa ERDOĞAN
Kafkas Üniversitesi, Türkiye
Hitit University, Türkiye
Hitit University, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of Fluorine Chemistry |
| Dergi ISSN | 0022-1139 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q3 |
| Makale Dili | İngilizce |
| Basım Tarihi | 02-2021 |
| Cilt No | 242 |
| Sayı | 1 |
| Sayfalar | 109718 / 0 |
| DOI Numarası | 10.1016/j.jfluchem.2020.109718 |
| Makale Linki | http://dx.doi.org/10.1016/j.jfluchem.2020.109718 |
| Özet |
| A new fluorinated naphthyl-acrylate based monomer was synthesized in three steps, namely the addition reaction of furan via Diels Alder cycloaddition reaction, acid catalyzed aromatization reaction and Schotten-Baumann esterification reaction, respectively. The structure of the precursors and the target compound was characterized comprehensively by FT-IR, UV–vis, 1H NMR, 13C NMR, 19F NMR and LC–MS/MS measurements. Atom transfer radical polymerization (ATRP) was used for the polymerization of 5,6,7,8-tetrafluoronaphthalen-1-yl acrylate. The successful polymerization of this novel monomer was verified by FT-IR and GPC analyses. Particularly, DSC and TGA analyses showed that the poly(5,6,7,8-tetrafluoronaphthalen-1-yl acrylate) has a glass transition temperature of 105−110 °C and starts to degrade after 150 °C. The results showed that the proposed monomer can be synthesized in yields overpassing 80 % by using the aforementioned reaction sequence. Our results revealed that 5,6,7,8-tetrafluoro naphthalen-1-yl acrylate could be acceptable as a promising monomer candidate in the field of synthetic polymer chemistry. |
| Anahtar Kelimeler |
| 19 F NMR | Acrylate | ATRP | Fluorinated aromatic monomer | Tetrafluoronaphthol |
Science Direct
A novel fluorinated monomer: Synthesis, characterization and ATRP of 5,6,7,8-tetrafluoronaphthalen-1-yl acrylate
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 5 |
| Google Scholar | 7 |