Access to polysubstituted naphthalenes and anthracenes via a retro-Diels Alder reaction
     
Yazarlar (4)
Esra Turan Akın Atatürk Üniversitesi, Türkiye
Doç. Dr. Musa ERDOĞAN Kafkas Üniversitesi, Türkiye
Arif Daştan Atatürk Üniversitesi, Türkiye
Nurullah Saraçoğlu Atatürk Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Tetrahedron
Dergi ISSN 0040-4020 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 09-2017
Cilt / Sayı / Sayfa 73 / 37 / 5537–5546 DOI 10.1016/j.tet.2017.07.058
Makale Linki http://dx.doi.org/10.1016/j.tet.2017.07.058
Özet
Naphthalene and anthracene nuclei are present in several natural and synthetic compounds. Due to their unique physical and chemical properties, access to functionalized naphthalenes and anthracenes has attracted the attention of both synthetic and medicinal chemists over the decades. In this study, successive Diels–Alder/retro-Diels–Alder reactions of dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate with various bicyclic alkenes in one pot to yield naphthalene and anthracene derivatives are reported. Using anti- and syn-cyclotrimers derived from the cyclotrimerization of benzobarrelene as alkene partner enabled efficient synthesis of trinaphthylene.
Anahtar Kelimeler
Tetrazine | retro-Diels-Alder | Naphthalene | Anthracene