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Access to polysubstituted naphthalenes and anthracenes via a retro-Diels Alder reaction      
Yazarlar
Esra Turan Akın
Türkiye
Doç. Dr. Musa ERDOĞAN Doç. Dr. Musa ERDOĞAN
Kafkas Üniversitesi, Türkiye
Arif Daştan
Atatürk Üniversitesi, Türkiye
Nurullah Saraçoğlu
Atatürk Üniversitesi, Türkiye
Özet
Naphthalene and anthracene nuclei are present in several natural and synthetic compounds. Due to their unique physical and chemical properties, access to functionalized naphthalenes and anthracenes has attracted the attention of both synthetic and medicinal chemists over the decades. In this study, successive Diels–Alder/retro-Diels–Alder reactions of dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate with various bicyclic alkenes in one pot to yield naphthalene and anthracene derivatives are reported. Using anti- and syn-cyclotrimers derived from the cyclotrimerization of benzobarrelene as alkene partner enabled efficient synthesis of trinaphthylene.
Anahtar Kelimeler
Tetrazine | retro-Diels-Alder | Naphthalene | Anthracene
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı TETRAHEDRON
Dergi ISSN 0040-4020
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 09-2017
Cilt No 73
Sayı 37
Sayfalar 5537 / 5546
Doi Numarası 10.1016/j.tet.2017.07.058
Makale Linki http://dx.doi.org/10.1016/j.tet.2017.07.058