Yazarlar |
Doç. Dr. Musa ERDOĞAN
Kafkas Üniversitesi, Türkiye |
Arif Daştan
Atatürk Üniversitesi, Türkiye |
Özet |
Syntheses of pyridazine derivatives of dibenzoazepine, starting from N-substituted-dibenzoazepines, are reported here for the first time. In the reaction sequence, N-substitute dibenzoazepine derivatives were synthesized and then, examined inverse electron demand Diels–Alder (IEDDA) reactions between N-substituted dibenzoazepine derivatives and tetrazines. While in some reactions, targeted products were obtained using phenyliodo-bis(trifluoroacetate) (PIFA), in other reactions, they were obtained directly with tetrazines which also behaved as the oxidizing agent. Structures of these compounds were fully characterized by NMR, IR, and HRMS spectroscopic techniques. |
Anahtar Kelimeler |
5H-dibenzo[b,f]azepine | Azepine | iminostilbene | inverse electron demand Diels–Alder | PIFA | pyridazine | tetrazine |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | SYNTHETIC COMMUNICATIONS |
Dergi ISSN | 0039-7911 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 12-2020 |
Cilt No | 50 |
Sayı | 24 |
Sayfalar | 3845 / 3853 |
Doi Numarası | 10.1080/00397911.2020.1828925 |
Makale Linki | https://www.tandfonline.com/doi/full/10.1080/00397911.2020.1828925 |