| Yazarlar |
Doç. Dr. Musa ERDOĞAN
Kafkas Üniversitesi, Türkiye |
| Özet |
| Guaiazulene, 1,4-dimethyl-7-isopropylazulene, is one of the non-benzenoid aromaticcompounds consisting of fused of the seven- and the five-membered ring. Guaiazulene is an importantnatural product and having great potential due to its unique optical and electronic properties. In thisstudy, a method for propargyl insertion into the C-4 methyl group of the guaiazulene is developed. Aone-pot reaction of the guaiazulene, LDA, and propargyl bromide in THF affords the corresponding anew propargyl-azulene hybrid derivative. Additionally, Diels-Alder cycloaddition reaction between thepropargyl-GA and tetraphenylcyclopentadienone was performed, and the cycloadduct was obtained withexcellent yield. The structures of new compounds were elucidated on the basis of extensivespectroscopic (IR, NMR, and UV-vis) data analysis. This approach may be potentially useful for thedevelopment of the new azulene derivatives. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | Ulusal alan endekslerinde (TR Dizin, ULAKBİM) yayımlanan tam makale |
| Dergi Adı | JOURNAL OF THE INSTITUTE OF SCIENCE AND TECHNOLOGY |
| Dergi ISSN | 0046-9750 |
| Dergi Tarandığı Indeksler | TR DİZİN |
| Makale Dili | İngilizce |
| Basım Tarihi | 12-2020 |
| Cilt No | 10 |
| Sayı | 4 |
| Sayfalar | 2747 / 2758 |
| Doi Numarası | 10.21597/jist.735838 |
| Makale Linki | https://doi.org/10.21597/jist.735838 |
| Atıf Sayıları |
