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Highly diastereoselective synthesis of a novel functionalized triepoxytrinaphthylene      
Yazarlar
Doç. Dr. Musa ERDOĞAN Doç. Dr. Musa ERDOĞAN
Kafkas Üniversitesi, Türkiye
Selçuk Eşsiz
Hakkari Üniversitesi, Türkiye
Fabrizio Fabris
Türkiye
Arif Daştan
Atatürk Üniversitesi, Türkiye
Özet
The high yielding synthesis of a novel benzocyclotrimer is herein presented. The syn-diastereomer is obtained as major product, presumably in virtue of the presence of an oxa-bridge of the bicylic components. The three oxa-bridges can be used for further functionalization, as well as the six bromine atoms of the three aromatic rings, as demonstrated in the aromatization of a mixture of anti-1 and syn-1 (3:7) leading to trinaphthylene.
Anahtar Kelimeler
Cyclotrimerization | copper | cup-shaped molecules | stereoselective reactions | aromatic compounds
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ARKIVOC
Dergi ISSN 1551-7004
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2018
Cilt No 2018
Sayı 3
Sayfalar 134 / 143
Doi Numarası 10.24820/ark.5550190.p010.408
Makale Linki https://doi.org/10.24820/ark.5550190.p010.408
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Google Scholar 1
Highly diastereoselective synthesis of a novel functionalized triepoxytrinaphthylene

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