Synthesis, characterization and effects on biochemical parameters of model organism Galleria mellonella L. (Lepidoptera: Pyralidae) of Cu(II) 4-cyanobenzoate with 4-cyanopyridine complex
Yazarlar (4)
Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye
Serkan Sugeçti Zonguldak Bulent Ecevit University, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Chemical Papers (Q3) | ||
| Dergi ISSN | 0366-6352 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 06-2023 |
| Cilt / Sayı / Sayfa | 77 / 9 / 5331–5342 | DOI | 10.1007/s11696-023-02865-6 |
| Makale Linki | http://dx.doi.org/10.1007/s11696-023-02865-6 | ||
| Özet |
| The structure of the title complex, C56H32Cu2N12O8, was characterized using elemental analysis, Fourier transform infrared (FT-IR) spectroscopy and single-crystal X-ray diffraction technique. In addition, the effects of the newly synthesized complex on metabolic, antioxidant and biochemical parameters of Galleria mellonella larvae were investigated. In the title dinuclear CuII complex, [Cu2(C6H4N2)4(C8H4NO2)4], the metal atom is chelated by one carboxylate group from 4-cyanobenzoate (CYNB) anion and coordinated by two 4-cyanopyridine (CYNP) anions; two carboxylate O atoms from the two CYNB anions bridge to the Cu atom, completing the six-coordination geometry. The two axial locations of the two 4-cyanopyridine (CYNP) N atoms complete the distorted octahedral coordination, which is formed by the four carboxylate O atoms in the equatorial plane around the CuII atom. In the crystal, the weak C–H … |
| Anahtar Kelimeler |
| 4-cyanobenzoate | 4-cyanopyridine | Copper complex | Galleria mellonella | Metabolic enzymes | Pest control | Transferase enzymes | XRD |