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Synthesis, structural characterization and determination of the nitro-containing explosives detection potential of supramolecular lanthanum complex and Lanthana nanoparticles    
Yazarlar
Doç. Dr. Füreya Elif ÖZTÜRKKAN Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Elaheh Teymouri
Türkiye
Mustafa Yüksek
İskenderun Teknik Üniversitesi, Türkiye
Elif Akhüseyin Yıldız
Türkiye
Doç. Dr. Mustafa SERTÇELİK Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Abdolali Alemi
Türkiye
Tuncer Hökelek
Türkiye
Özet
A novel nanoparticle sized complex, [La(HO-C6H4-CH2COO)3(H2O)].(H2O), has been prepared by the reaction of LaIII ion and a versatile carboxylate ligand, 4-hydroxyphenylacetatic acid. The obtained complex was structurally characterized by using single crystal X-ray diffraction, SEM-EDS and FT-IR spectroscopy. Then, we synthesized La2O3 nanoparticles by the calcination of the complex and characterized its features by powder X-ray diffraction and SEM analysis. Average particle sizes of the complex and La2O3 particles were determined 19.6 nm and 44.02 nm, respectively. The bulk form of La2O3 (bulk) was bought commercially. The linear optical absorption traces of all materials were recorded by using UV–Vis spectrophotometer. The nitro-containing explosive detection potentials of complex, nanoparticles and bulk materials were investigated by using fluorescence spectrophotometer which is measured the fluorescence quenching of these three materials in nitro-containing media. It was found that all of the studied materials are good candidates especially for the detection of nitroaromatic compounds.
Anahtar Kelimeler
4-hydroxyphenylacetic acid | Fluorescence | Lanthanum complex | Nitro-containing media | XRD
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Materials Science & Engineering B
Dergi ISSN 0921-5107
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q2
Makale Dili Türkçe
Basım Tarihi 04-2023
Cilt No 290
Sayı 1
Doi Numarası 10.1016/j.mseb.2023.116331
Makale Linki http://dx.doi.org/10.1016/j.mseb.2023.116331