The superiority of the classical synthesis compared to the hydrothermal synthesis upon the structural, optical absorption and fluorescent properties of new Cd(II) 3-fluorobenzoate complexes with Pyridine-3-carboxamide/Pyridine-3-carboxylate

ÖZTÜRKKAN, FÜREYA ELİF; SERTÇELİK, MUSTAFA; Yüksek, Mustafa; Elmalı, Ayhan; Şahin, Ertan

doi:10.1016/j.ica.2020.119694

The superiority of the classical synthesis compared to the hydrothermal synthesis upon the structural, optical absorption and fluorescent properties of new Cd(II) 3-fluorobenzoate complexes with Pyridine-3-carboxamide/Pyridine-3-carboxylate

Yazarlar (5)

Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye

Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye

Mustafa Yüksek Kafkas Üniversitesi, Türkiye

Ayhan Elmalı Atatürk Üniversitesi, Türkiye

Ertan Şahin Ankara Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Inorganica Chimica Acta (Q4)
Dergi ISSN	0020-1693 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	SCI-Expanded
Makale Dili	İngilizce	Basım Tarihi	09-2020
Kabul Tarihi	–	Yayınlanma Tarihi	01-09-2020
Cilt / Sayı / Sayfa	509 / 1 / 119694–0	DOI	10.1016/j.ica.2020.119694
Makale Linki	https://linkinghub.elsevier.com/retrieve/pii/S0020169320304163

Özet

Three new cadmium–3-fluorobenzoate complexes with pyridine-3-carboxamide/pyridine-3-carboxylate complexes, namely, [Cd2(C7H4FO2)4(C6H6N2O)2(H2O)2] (1), [Cd2(C7H4FO2)4(C6H6N2O)2(H2O)2] (2), [Cd(C7H4FO2)(C6H4NO2)(H2O)] (3) were obtained under classical and two different hydrothermal conditions, respectively. The structures of all prepared complexes were characterized by elemental analysis, FT-IR and ¹H NMR spectroscopy, TGA/DTA and single crystal X-ray analyses. In addition, the structural features of the complexes were studied theoretically by Hirshfeld surface analysis and the X-ray diffraction analyses were supported. It was determined that the carboxylate groups of 3-fluorobenzoate and pyridine-3-carboxylate behaved as chelating bidentate ligands. Hirshfeld surface analysis indicated that H⋯H, H⋯O/O⋯H, H⋯C/C⋯H, H⋯F/F⋯H and C⋯C interactions are the significant contributors to the crystal packing of the synthesized complexes. The thermal stabilities of the synthesized complexes have been investigated and the results showed that the complexes display thermal stability about 100 °C and the decomposition product of anhydrous complexes was CdO. The linear absorption and fluorescence (emission) properties of the complexes were investigated by using UV–Vis and Fluorescence spectroscopic techniques, respectively. It was found that the complex 1 which is synthesized by classical method has got very good emission intensity compared to the materials reported in the literature. This makes the complex 1 potential member for image acquisition without lens and filter, security printing, data recording and storage and laser applications, if its solid form can be done. In addition, it was determined that the classical synthesis has superiority according to the hydrothermal synthesis on the structural, optical absorption and fluorescence properties of the complex.

Anahtar Kelimeler

Science Direct

Atıf Sayıları
Scopus	6

The superiority of the classical synthesis compared to the hydrothermal synthesis upon the structural, optical absorption and fluorescent properties of new Cd(II) 3-fluorobenzoate complexes with Pyridine-3-carboxamide/Pyridine-3-carboxylate

Dergi Adı	INORGANICA CHIMICA ACTA
Yayıncı	Elsevier B.V.
Açık Erişim	Hayır
ISSN	0020-1693
E-ISSN	1873-3255
CiteScore	5,5
SJR	0,393
SNIP	0,638

The superiority of the classical synthesis compared to the hydrothermal synthesis upon the structural, optical absorption and fluorescent properties of new Cd(II) 3-fluorobenzoate complexes with Pyridine-3-carboxamide/Pyridine-3-carboxylate

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