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Synthesis, Characterization, and Antibacterial Activity of Cd(II) Complexes with 3-/4-Fluorobenzoates and 3-Hydroxypiridine as Co-Ligands     
Yazarlar
Doç. Dr. Mustafa SERTÇELİK Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye
Durman Murat
Türkiye
Özet
Abstract: In this study, two new complexes of Cd(II) 4-fluorobenzoate (4-FB)/3-fluorobenzoate (3-FB) with 3-hydroxypyridine (3-HPY) have been synthesized and structural characterizations have been performed by using elemental analysis, FT-IR spectroscopy, and single-crystal X-ray diffraction methods. In both complexes, the metal atom is chelated by two carboxylate groups from two 4- or 3-fluorobenzoate anions and coordinated by two 3-hydroxypyridine (HPY) molecules. In both complexes, an oxygen atom of carboxylate from the adjacent anion bridges to the Cd atom, completing the distorted seven-coordination geometry. The only difference between complexes is the positions of fluorine atoms in fluorobenzoic acids (4-fluorobenzoic acid (complex 1) and 3-fluorobenzoic acid (complex 2)). Antibacterial resistance of two new complexes to some bacteria has been investigated.
Anahtar Kelimeler
3-fluorobenzoic acid | 3-hydroxypyridine | 4-fluorobenzoic acid | antibacterial | cadmium(II) complex | X-ray diffraction
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Russian Journal of Inorganic Chemistry
Dergi ISSN 0036-0236
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 09-2020
Cilt No 65
Sayı 9
Sayfalar 1351 / 1359
Doi Numarası 10.1134/S0036023620090168
Makale Linki http://link.springer.com/10.1134/S0036023620090168