Yazarlar |
Nurcan Akduran
Türkiye |
Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye |
Ömer Aydoğdu
Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
Özet |
The mononuclear title cadmium complex, [Cd(C10H14N2O)2(C8H4NO2)2(H2O)2], is centrosymmetric and contains two water molecules, two 4-cyanobenzoate (CB) ligands and two diethylnicotinamide (DENA) ligands. All the ligands are coordinated to the CdII atom in a monodentate mode. The four nearest O atoms around the CdII atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination sphere being completed by the two pyridine N atoms of the DENA ligands at distances of 2.3336(13)Å. The dihedral angle between the carboxylate group and the adjacent benzene ring is 8.75(16)°, while the benzene and pyridine rings are oriented at a dihedral angle of 57.83(5)°. The water molecules exhibit both intramolecular [to the non-coordinating carboxylate O atom, enclosing an S(6) hydrogen-bonding motif, where O⋯O = 2.670(2)Å] and intermolecular [to the amide carbonyl O atom, enclosing an R 2 2(16) ring motif, where O⋯O = 2.781(2)Å] O - H⋯O hydrogen bonds. The latter lead to the formation of supramolecular chains propagating along [110]. |
Anahtar Kelimeler |
cadmium | crystal structure | transition metal complexes of benzoic acid and nicotinamide derivatives |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | Acta Crystallographica Section E Crystallographic Communications |
Dergi ISSN | 2056-9890 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 11-2016 |
Cilt No | 72 |
Sayı | 12 |
Sayfalar | 1827 / 1829 |
Doi Numarası | 10.1107/S2056989016018247 |
Makale Linki | http://scripts.iucr.org/cgi-bin/paper?S2056989016018247 |