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Diaquabis(4-formylbenzoato-κO1)bis-(nicotinamide-κN1)copper(II)   
Yazarlar
Doç. Dr. Mustafa SERTÇELİK Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye
Çaylak Delibaş Nagihan
Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Özet
In the title complex, [Cu(C8H5O3) 2(C6H6N2O)2(H 2O)2], the CuII cation is located on an inversion center and is coordinated by two 4-formylbenzoate (FB) anions, two nicotinamide (NA) ligands and two water molecules in an elongated distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 23.00 (10)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 85.34 (4)°. An intramolecular O - H⋯O hydrogen bond occurs between coordinating water molecule and the carboxylate group. In the crystal, N - H⋯O, O - H⋯O and weak C - H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular network. A weak C - H⋯π interaction also occurs in the crystal. © 2012 International Union of Crystallography.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce
Basım Tarihi 07-2012
Cilt No 68
Sayı 7
Sayfalar 1010 / 1011
Doi Numarası 10.1107/S1600536812028814
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S1600536812028814
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
SCOPUS 2
Diaquabis(4-formylbenzoato-κO1)bis-(nicotinamide-κN1)copper(II)

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