Diaquabis(N,N-diethylnicotinamide- κN1)bis(4-formylbenzoato- κO)manganese(II)
  
Yazarlar (5)
Doç. Dr. Mustafa SERTÇELİK Kafkas Üniversitesi, Türkiye
Bar Tercan Karabük Üniversitesi, Türkiye
Ertan Ahin Atatürk Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online (Q4)
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 03-2009
Cilt / Sayı / Sayfa 65 / 3 / – DOI 10.1107/S1600536809006047
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S1600536809006047
Özet
The title compound, [Mn(C8H5O3) 2(C10H14N2O)2(H 2O)2], contains one MnII atom lying on an inversion centre, two 4-formyl-benzoate and two diethyl-nicotinamide ligands and two coordinated water mol-ecules. All ligands are monodentate. The four O atoms around the Mn atom form a slightly distorted equatorial plane, while the distorted octa-hedral coordination is completed by the two N atoms in the axial positions. An intra-molecular O - H⋯O hydrogen bond occurs in the complex. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules through an R 2 2(16) ring motif, forming a one-dimensional chain along the a axis. The π-π contact between the pyridyl rings [centroid-centroid distance = 3.629 (2) Å] may further stabilize the structure.
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