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catena-Poly[[(4-formylbenzoato-κO1)(isonicotinamide- N1)zinc(II)]-µ-4-formylbenzoato- κ2O1:O1’]     
Yazarlar
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Filiz Yılmaz
Anadolu Üniversitesi, Türkiye
Mustafa Barış Tercan
Karabük Üniversitesi, Türkiye
Doç. Dr. Mustafa SERTÇELİK Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
In the title compound, [Zn(C8H5O3) 2(C6H6N2O)] n , the ZnII ion is tetrahedrally coordinated by two formyl-benzoate (FB) and one isonicotinamide (INA) ligands while symmetry-related FB ligands bridge adjacent ZnII ions, forming polymeric chains along the b axis. The carboxyl-ate groups in the two FB ions are twisted away from the attached benzene ring by 9.07 (2) and 26.2 (2)°. The two benzene rings of the FB ions are oriented at a dihedral angle of 81.30 (5)°. In the crystal, adjacent polymeric chains inter-act via N- H⋯O and C- H⋯O hydrogen bonds, π-π contacts between the formyl-benzoate rings [centroid-centroid distance = 3.7736 (8) Å] and weak C- H⋯π inter-actions, forming a three-dimensional network.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce
Basım Tarihi 11-2009
Cilt No 65
Sayı 11
Sayfalar 1399 / 1400
Doi Numarası 10.1107/S160053680904241X
Makale Linki http://scripts.iucr.org/cgi-bin/paper?S160053680904241X