| Yazarlar |
Doç. Dr. Bedrettin SAVAŞ
Kafkas Üniversitesi, Türkiye |
Temel Öztürk
Giresun Üniversitesi, Türkiye |
| Özet |
| The synthesis of the block copolymer was carried out using the RAFT polymerization technique and the ring-opening polymerization (ROP) technique using a novel two functional initiator (RAFT-ROP agent). For this purpose, RAFT-ROP agent was obtained using 5-bromo-2- hydroxybenzaldehyde and potassium salt of ethyl xanthogenate. RAFT-macro agent was synthesized by ROP of ɛ-caprolactone (CL) with RAFT-ROP agent. Then, poly(ɛ-caprolactone-b-styrene) block copolymer was synthesized using RAFT polymerization in the presence of RAFT-macro agent using styrene. The products were characterized using GPC, FT-IR and 1H-NMR analyses. Decomposition temperatures of the block copolymer were monitored by TGA method. Spectroscopic and thermal analyses revealed that the reactions were successfully carried out. |
| Anahtar Kelimeler |
| Novel Two Functional Initiator,RAFT-Macro Agent,Block Copolymer,RAFT Polymerization,Ring-Opening Polymerization (ROP) |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | Ulusal alan endekslerinde (TR Dizin, ULAKBİM) yayımlanan tam makale |
| Dergi Adı | Journal of the Institute of Science and Technology |
| Dergi ISSN | 2146-0574 |
| Dergi Tarandığı Indeksler | TR DİZİN |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2020 |
| Sayı | 3 |
| Sayfalar | 1759 / 1766 |
| Doi Numarası | 10.21597/jist.686682 |
| Makale Linki | http://dx.doi.org/10.21597/jist.686682 |
| Atıf Sayıları |
