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Synthesis and Characterization of Poly(Ԑ-caprolactone-b-Styrene) Block Copolymer by Ring-Opening Polymerization and Reversible Addition-Fragmentation Chain Transfer Polymerization    
Yazarlar
Doç. Dr. Bedrettin SAVAŞ Doç. Dr. Bedrettin SAVAŞ
Kafkas Üniversitesi, Türkiye
Temel Öztürk
Giresun Üniversitesi, Türkiye
Özet
The synthesis of the block copolymer was carried out using the RAFT polymerization technique and the ring-opening polymerization (ROP) technique using a novel two functional initiator (RAFT-ROP agent). For this purpose, RAFT-ROP agent was obtained using 5-bromo-2- hydroxybenzaldehyde and potassium salt of ethyl xanthogenate. RAFT-macro agent was synthesized by ROP of ɛ-caprolactone (CL) with RAFT-ROP agent. Then, poly(ɛ-caprolactone-b-styrene) block copolymer was synthesized using RAFT polymerization in the presence of RAFT-macro agent using styrene. The products were characterized using GPC, FT-IR and 1H-NMR analyses. Decomposition temperatures of the block copolymer were monitored by TGA method. Spectroscopic and thermal analyses revealed that the reactions were successfully carried out.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü Ulusal alan endekslerinde (TR Dizin, ULAKBİM) yayımlanan tam makale
Dergi Adı Journal of the Institute of Science and Technology
Dergi ISSN 2146-0574
Dergi Tarandığı Indeksler TR DİZİN
Makale Dili İngilizce
Basım Tarihi 09-2020
Sayı 3
Sayfalar 1759 / 1766
Doi Numarası 10.21597/jist.686682
Makale Linki http://dx.doi.org/10.21597/jist.686682