| Yazarlar |
Mehmet Salih Ağırtaş
Van Yüzüncü Yıl Üniversitesi, Türkiye |
|
Derya Güngördü Solğun
Türkiye |
Doç. Dr. Ümit YILDIKO
Kafkas Üniversitesi, Türkiye |
|
Abdullah Özkartal
Van Yüzüncü Yıl Üniversitesi, Türkiye |
| Özet |
| The 4-(2-[3,4-dimethoxyphenoxy] phenoxy) phthalonitrile was synthesized as the starting material of new syntheses. Zinc, copper, and cobalt phthalocyanines were achieved by reaction of starting compound with $Zn(CH_3 COO)_2, CuCl_2, and CoCl_2$ metal salts. Basic spectroscopic methods such as nuclear magnetic resonance electronic absorption, mass and infrared spectrometry were used in the structural characterization of the compounds. Absorption, excitation, and emission measurements of the fluorescence zinc phthalocyanine compound were also investigated in THF. Then, structural, energy, and electronic properties for synthesized metallophthalocyanines were determined by quantum chemical calculations, including the DFT method. The bandgap of HOMO and LUMO was determined to be chemically active. Global reactivity (I, A, η, s, μ, χ, ω) and nonlinear properties were studied. In addition, molecular electrostatic potential (MEP) maps were drawn to identify potential reactive regions of metallophthalocyanine (M-Pc) compounds. Photovoltaic performances of phthalocyanine compounds for dye sensitive solar cells were investigated. The solar conversion efficiency of DSSC based on copper, zinc, and cobalt phthalocyanine compounds was 1.69%, 1.35%, and 1.54%, respectively. The compounds have good solubility and show nonlinear optical properties. Zinc phthalocyanine gave fluorescence emission. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | TURKISH JOURNAL OF CHEMISTRY |
| Dergi ISSN | 1300-0527 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 12-2020 |
| Cilt No | 44 |
| Sayı | 6 |
| Sayfalar | 1574 / 1586 |
| Makale Linki | https://journals.tubitak.gov.tr/chem/lastIssue.htmjsessionid=5C7272C80D387A27370C209B14FDD867 |
