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Solid-liquid phase equilibria in the ternary systems H2O+ZnCl2+NaCl at temperatures of 298, 313 and 333 K    
Yazarlar (3)
Dr. Öğr. Üyesi Sevilay DEMİRCİ Dr. Öğr. Üyesi Sevilay DEMİRCİ
Kafkas Üniversitesi, Türkiye
Doç. Dr. Vedat ADIGÜZEL Doç. Dr. Vedat ADIGÜZEL
Kafkas Üniversitesi, Türkiye
Ömer Şahin
İstanbul Teknik Üniversitesi, Türkiye
Devamını Göster
Özet
In this study, an economic separation method is suggested with the use of phase equilibria in order to ensure the recycling of ZnCl2, the industrial waste amount of which is very high, and to prevent it from an environmental pollutant. Sodium chloride–zinc chloride–water systems were examined by the isothermal method at temperatures of 298, 313 and 333 K. The analyses of the liquid and solid phases were used to determine the composition of the solid phase using the Schreinemaker’s graphic method. The solid–liquid phase equilibrium and viscosity data belonging to all the ternary systems were identified and the solubility and viscosity changes with temperature were compared. The viscosity values were inversely proportional to the temperature as the amount of ZnCl2 in the solution increased. NaCl, 2NaCl ZnCl2 nH2O (n: 2, 0), ZnCl2 salts were observed at 298, 313 and 333 K in the solid phases that are in equilibrium with the liquid phase at the invariant point.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Journal of the Serbian Chemical Society
Dergi ISSN 0352-5139 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili İngilizce
Basım Tarihi 02-2022
Cilt No 87
Sayı 2
Sayfalar 263 / 273
Doi Numarası 10.2298/JSC210419053D
Makale Linki http://dx.doi.org/10.2298/jsc210419053d