The Solubilities and Physicochemical Properties of NaH2PO2-NaCl-H2O, NaH2PO2-Zn(H2PO2)2-H2O, and NaCl-Zn(H2PO2)2-H2O Ternary Systems and in NaH2PO2-NaCl-Zn(H2PO2)2-H2O Quaternary System at 298.15 K
  
Yazarlar (3)
Dr. Öğr. Üyesi Sevilay DEMİRCİ Kafkas Üniversitesi, Türkiye
Doç. Dr. Vedat ADIGÜZEL Kafkas Üniversitesi, Türkiye
Ömer Şahin Siirt Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Chemical & Engineering Data
Dergi ISSN 0021-9568 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 07-2016
Cilt / Sayı / Sayfa 61 / 7 / 2292–2298 DOI 10.1021/acs.jced.5b00988
Makale Linki http://dx.doi.org/10.1021/acs.jced.5b00988
Özet
The physicochemical properties and solubilities of NaH2PO2–Zn(H2PO2)2–H2O, NaH2PO2–NaCl–H2O, and NaCl–Zn(H2PO2)2–H2O ternary systems and in NaH2PO2–NaCl–Zn(H2PO2)2–H2O quaternary system at 298.15 K were investigated via the isothermal method. Invariant point compositions represent the quaternary system were characterized as the following: 10.65% mass NaCl, 32.51% mass NaH2PO2, 6.50% mass Zn(H2PO2)2, and 50.34% mass H2O. In solid phases, the salts of Zn(H2PO2)2.H2O, NaCl and NaH2PO2·H2O were recognized. The crystallization area of the salts were obtained as (i) 79.04% Zn(H2PO2)2, (ii) 18.62% NaCl and (iii) 2.34% NaH2PO2. Being the least soluble salt, Zn(H2PO2)2 has the largest crystallization area when compared with other salts present in the medium. According to the results, the crystallization area of was the largest in comparison with those of other salts and …
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