Study of the solubility in Na–Ba–Cl–H2O, Na–Ba–H2PO2–H2O, Na–Cl–H2PO2–H2O, and Ba–Cl–H2PO2–H2O ternaries, and in Na+, Ba2+/Cl−, (H2PO2)−//H2O reciprocal quaternary system at 0 °C   
Yazarlar (3)
Hasan Erge
Van Yüzüncü Yıl Üniversitesi, Türkiye
Doç. Dr. Vedat ADIGÜZEL Kafkas Üniversitesi, Türkiye
Vahit Alişoğlu
Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Fluid Phase Equilibria
Dergi ISSN 0378-3812 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 04-2013
Cilt No 344
Sayfalar 13 / 18
DOI Numarası 10.1016/j.fluid.2012.12.033
Makale Linki http://dx.doi.org/10.1016/j.fluid.2012.12.033
Özet
The solubility and the physicochemical properties (density and conductivity) in the Na–Ba–Cl–H2O, Na–Ba–H2PO2–H2O, Na–Cl–H2PO2–H2O, and Ba–Cl–H2PO2–H2O ternaries, and in Na+, Ba2+/Cl−, (H2PO2)−//H2O reciprocal quaternary systems at 0°C were investigated using the isothermal method. Two invariant point were determined in Na+, Ba2+/Cl−, (H2PO2)−//H2O reciprocal quaternary system. The composition of invariant point of the first (as a weight) was determined as fallowing; 15.03% mass NaCl, 12.36% mass BaCl2, 2.86% mass Ba(H2PO2)2, and 69.75% mass H2O. It was plotted that the liquid phase and the following three solid phases were in equilibrium at the invariant point at 0°C. These are NaCl, BaCl2·H2O, Ba(H2PO2)2·H2O. As for the composition of the second invariant point (as a weight) was determined as follows: 1.06% mass NaCl, 43.98% mass NaH2PO2, 0.51% mass Ba(H2PO2)2 …
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