| Yazarlar (5) |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Vijdan Öztürk
Türkiye |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Doç. Dr. Vedat ADIGÜZEL
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
| Özet |
| In the mononuclear NiII title complex, [Ni(C7H4FO2)2(C6H6N2O)2(H2O)2], the NiII atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluorobenzoate ligands and two water molecules in a distorted N2O4 octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 8.95 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 75.01 (7)°. The water molecule links the adjacent carboxylate O atom via an intramolecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O, N—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds link the molecules into a three-dimensional network. π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.7287 (11) Å] is also observed. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Acta Crystallographica Section E Structure Reports Online |
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | SCI |
| Makale Dili | Türkçe |
| Basım Tarihi | 01-2011 |
| Cilt No | 67 |
| Sayı | 2 |
| Sayfalar | 1638 / 1639 |
| Doi Numarası | 10.1107/S1600536811044771 |
| Makale Linki | http://dx.doi.org/10.1107/s1600536811044771 |
| Atıf Sayıları | |
| Google Scholar | 3 |
