| Yazarlar (5) |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Vijdan Öztürk
Türkiye |
Doç. Dr. Vedat ADIGÜZEL
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye |
| Özet |
| The asymmetric unit of the title mononuclear CuII complex, [Cu(C7H4BrO2)2(C6H6N2O)2(H2O)2], contains one half-molecule, the CuII atom being located on an inversion center. The unit cell contains two nicotinamide (NA), two 4-bromobenzoate (PBB) ligands and two coordinated water molecules. The four O atoms in the equatorial plane around the CuII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 22.17 (16)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 82.80 (6)°. In the crystal, N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. A weak C—H⋯π interaction is also observed. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Acta Crystallographica Section E Structure Reports Online |
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | SCI |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2011 |
| Cilt No | 67 |
| Sayı | 9 |
| Sayfalar | 1317 / 1318 |
| Doi Numarası | 10.1107/S1600536811034787 |
| Makale Linki | http://dx.doi.org/10.1107/s1600536811034787 |
| Atıf Sayıları | |
| Google Scholar | 12 |
