Yazarlar (5) |
![]() Kafkas Üniversitesi, Türkiye |
![]() Kafkas Üniversitesi, Türkiye |
![]() Türkiye |
![]() Kafkas Üniversitesi, Türkiye |
![]() Hacettepe Üniversitesi, Türkiye |
Özet |
In the crystal structure of the title MnII complex, [Mn(C7H4BrO2)2(C10H14N2O)2(H2O)2], the MnII cation is located on an inversion center and coordinated by two diethylnicotinamide (DENA) ligands, two 4-bromobenzoate (PBB) anions and two water molecules in a distorted octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 3.25 (14)°. In the molecule, the pyridine ring and the benzene ring are oriented at a dihedral angle of 77.24 (5)°. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into a two-dimensional network. Weak intermolecular C—H⋯O hydrogen bonds and π–π interactions between the pyridine rings of neighbouring molecules [centroid–centroid distance = 3.537 (1) Å] further consolidate the crystal packing. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
Dergi Adı | Acta Crystallographica Section E Structure Reports Online |
Dergi ISSN | 1600-5368 |
Dergi Tarandığı Indeksler | SCI |
Makale Dili | İngilizce |
Basım Tarihi | 09-2011 |
Cilt No | 67 |
Sayı | 9 |
Sayfalar | 1209 / 1210 |
Doi Numarası | 10.1107/S1600536811031412 |
Makale Linki | http://dx.doi.org/10.1107/s1600536811031412 |
Atıf Sayıları | |
Google Scholar | 1 |