Di-μ-nicotinamide-κ2N1:O;κ2O:N1-bis[aquabis(4-bromobenzoato)-κO;κ2O,O′-manganese(II)]
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Vijdan Öztürk
Türkiye
Doç. Dr. Vedat ADIGÜZEL
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
|
||
| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2011 |
| Cilt / Sayı / Sayfa | 67 / 8 / 1128–1129 | DOI | 10.1107/S1600536811028492 |
| Makale Linki | http://dx.doi.org/10.1107/s1600536811028492 | ||
| Özet |
| In the centrosymmetric dinuclear title compound, [Mn2(C7H4BrO2)4(C6H6N2O)2(H2O)2], the MnII atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, three O atoms from two 4-bromobenzoate ligands and one water molecule in a distorted octahedral geometry. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 10.89 (16) and 8.4 (2)°, while the benzene rings are oriented at a dihedral angle of 6.09 (13)°. Intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π interactions, indicated by short centroid–centroid distances [3.845 (2) Å between the benzene rings, 3.650 (2) Å between the pyridine rings and 3.700 (3) Å between the benzene and pyridine rings] further stabilize the structure. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 6 |