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A novel thiophene-based D-π-A type organic material: Synthesis, characterization and Schottky diode applications     
Yazarlar
Musa Erdoğan
Kafkas Üniversitesi, Turkey
Ali Rıza Deniz
Hakkari Üniversitesi, Turkey
Zakir Çaldıran
Ardahan Üniversitesi, Turkey
Özet
Herein, a newly designed π-conjugated D-π-A type organic material, namely TPA-T-DCV 9, was synthesized in excellent yield by introducing triphenylamine as electron donor and dicyanovinyl unit attached to the benzene ring as electron acceptor at positions 3 and 4 of the central thiophene skeleton as π-linker, respectively. The Au/TPA-T-DCV 9/p-Si/Al diode was fabricated by using TPA-T-DCV 9 material as interface material. The electrical properties of this diode were analyzed using the current–voltage (I-V) curve of the diode and it was determined that the use of TPA-T-DCV 9 material improved electrical charecteris. The I-V measuments of the diode are performed between 100 K and 325 K. According to calculations from TE theory, n value changes between 4.04 and 1.19 value for increasing temperature value, Φb value changes between 0.33 and 0.81 eV value with increasing temperature. In addition, Rs values calculated from Cheung functions vary between 2004 Ω and 10470 Ω with decreasing temperature value. From the temperature-dependent I-V graphs of the diode, it was determined that the diode parameters were in a strong change depending on the temperature gradient. The frequency response of capacitance–voltage (C-V) measurements of Au/TPA-T-DCV 9/p-Si/Al diode was investigated.
Anahtar Kelimeler
Capacitance-voltage | Current-voltage | D-π-A | Dicyanovinyl | Schttoky diode | Triphenylamine
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Journal of Photochemistry and Photobiology A: Chemistry
Dergi ISSN 1010-6030
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q2
Makale Dili Türkçe
Basım Tarihi 09-2023
Cilt No 443
Sayı 1
Doi Numarası 10.1016/j.jphotochem.2023.114877
Makale Linki http://dx.doi.org/10.1016/j.jphotochem.2023.114877