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Synthesis, structural characterization and determination of the nitro-containing explosives detection potential of supramolecular lanthanum complex and Lanthana nanoparticles      
Yazarlar
 Füreya Elif ÖZTÜRKKAN Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Elaheh Teymouri
University of Tabriz, Iran
Mustafa Yüksek
Iskenderun Technical University, Turkey
Elif Akhüseyin Yıldız
Ankara Üniversitesi, Turkey
 Mustafa SERTÇELİK Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye
Abdolali Alemi
University of Tabriz, Iran
 Hacali NECEFOĞLU Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
A novel nanoparticle sized complex, [La(HO-C6H4-CH2COO)3(H2O)].(H2O), has been prepared by the reaction of LaIII ion and a versatile carboxylate ligand, 4-hydroxyphenylacetatic acid. The obtained complex was structurally characterized by using single crystal X-ray diffraction, SEM-EDS and FT-IR spectroscopy. Then, we synthesized La2O3 nanoparticles by the calcination of the complex and characterized its features by powder X-ray diffraction and SEM analysis. Average particle sizes of the complex and La2O3 particles were determined 19.6 nm and 44.02 nm, respectively. The bulk form of La2O3 (bulk) was bought commercially. The linear optical absorption traces of all materials were recorded by using UV–Vis spectrophotometer. The nitro-containing explosive detection potentials of complex, nanoparticles and bulk materials were investigated by using fluorescence spectrophotometer which is measured the fluorescence quenching of these three materials in nitro-containing media. It was found that all of the studied materials are good candidates especially for the detection of nitroaromatic compounds.
Anahtar Kelimeler
Lanthanum complex | 4-hydroxyphenylacetic acid | XRD | Fluorescence | Nitro-containing media
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
Dergi ISSN 0921-5107
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q2
Makale Dili İngilizce
Basım Tarihi 04-2023
Cilt No 290
Sayı 116331
Sayfalar 1 / 9
Doi Numarası 10.1016/j.mseb.2023.116331
Makale Linki http://dx.doi.org/10.1016/j.mseb.2023.116331