| Yazarlar |
Doç. Dr. Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye |
Nagihan Çaylak Delibaş
Sakarya Üniversitesi, Turkey |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
|
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
| Özet |
| The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu2(C8H5O3)4(C 6H6N2O)4], contains one half of the complex molecule. The CuII atoms are bridged by the carboxylate groups of two 4-formylbenzoate (FOB) anions. Besides the two bridging FOB anions, one additional chelating FOB anion and two isonicotinamide (INA) ligands complete the distorted CuN2O4 octahedral coordination of each Cu2+ cation. Within the asymmetric unit, the benzene and pyridine rings are oriented at dihedral angles of 25.1 (3) and 12.6 (3)°, respectively. In the crystal, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π contacts between the pyridine rings [shortest centroid-centroid distance = 3.821 (3) Å] may further stabilize the crystal structure. One of the formyl groups of the two FOB anions is disordered over two sets of sites with an occupancy ratio of 0.65:0.35. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 2056-9890 |
| Makale Dili | İngilizce |
| Basım Tarihi | 05-2013 |
| Cilt No | 69 |
| Sayı | 5 |
| Doi Numarası | 10.1107/S1600536813010908 |
| Atıf Sayıları | |
| WoS | 12 |
| SCOPUS | 12 |
| Google Scholar | 23 |
