| Yazarlar |
Mustafa Sertcelik
|
|
Nagihan Caylak Delibas
|
|
Hacali Necefoglu
|
|
Tuncer Hokelek
|
| Özet |
| In the title complex, [Co(C8H5O3) 2(C6H6N2O)2(H 2O)2], the CoII cation is located on an inversion center and is coordinated by two 4-formyl-benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol-ecules. The four O atoms in the equatorial plane around the CoII cation form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 23.91 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 88.84 (4)°. The coordinating water mol-ecule links with the carboxyl-ate group via an intra-molecular O-H⋯O hydrogen bond. In the crystal, N-H⋯O, O-H⋯O and weak C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network. π-π stacking between the parallel benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.8505 (8) Å] may further stabilize the structure. A weak C-H⋯π inter-action also occurs in the crystal. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 16.3 | mean σ(C-C) = 0.002 Å | R factor = 0.026 | single-crystal X-ray study | T = 100 K | wR factor = 0.069 |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 2056-9890 |
| Makale Dili | İngilizce |
| Basım Tarihi | 80-2012 |
| Cilt No | 68 |
| Doi Numarası | 10.1107/S1600536812032205 |
