catena-Poly[[[bis(4-ethylbenzoato-κ2O,O')lead(II)]-μ-nicotinamide-κ2N1:O] monohydrate]

Hökelek, Tuncer; Tercan, Bar; Ahin, Ertan; Akta, Vedat; NECEFOĞLU, HACALİ

doi:10.1107/S1600536811026535

catena-Poly[[[bis(4-ethylbenzoato-κ²O,O')lead(II)]-μ-nicotinamide-κ²N¹:O] monohydrate]

Yazarlar (5)

Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye

Bar Tercan
Karabük Üniversitesi, Türkiye

Ertan Ahin
Atatürk Üniversitesi, Türkiye

Vedat Akta
Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online
Dergi ISSN	1600-5368
Makale Dili	İngilizce	Basım Tarihi	08-2011
Cilt / Sayı / Sayfa	67 / 8 / –	DOI	10.1107/S1600536811026535
Makale Linki	https://doi.org/10.1107/s1600536811026535
UAK Araştırma Alanları	Fen Bilimleri ve Matematik

Özet

In the crystal structure of the polymeric title compound, {[Pb(C 9H 9O 2) 2(C 6H 6N 2O)]·H 2O} n , the six-coordinate Pb ^II ion is chelated by two 4-ethyl-benzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxyl-ate groups of the PEB ions are twisted away from the attached benzene rings by 4.0 (6) and 13.3 (5)°. The two benzene rings of the PEB ions bonded to the same metal ion are oriented at a dihedral angle of 87.4 (3)°. In the polymeric chain, the NA ligand is linked to one of the carboxyl-ate groups via N - H⋯O hydrogen bonding. In the crystal, adjacent polymeric chains inter-act via N - H⋯O and weak C - H⋯O hydrogen bonds; and the lattice water molecule links with the polymeric chains via N - H⋯O and O - H⋯O hydrogen bonding. π-π stacking between the benzene and the pyridine rings [centroid-centroid distance = 3.805 (5) Å] and weak C - H⋯π interactions are also observed in the crystal structure.

Anahtar Kelimeler

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları

catena-Poly[[[bis(4-ethylbenzoato-κ²O,O')lead(II)]-μ-nicotinamide-κ²N¹:O] monohydrate]

catena-Poly[[[bis(4-ethylbenzoato-κ2O,O')lead(II)]-μ-nicotinamide-κ2N1:O] monohydrate]

Paylaş

catena-Poly[[[bis(4-ethylbenzoato-κ²O,O')lead(II)]-μ-nicotinamide-κ²N¹:O] monohydrate]