catena-Poly[[[bis(4-ethylbenzoato-κ2O,O')lead(II)]-μ-nicotinamide-κ2N1:O] monohydrate]
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Ertan Ahin
Atatürk Üniversitesi, Türkiye
Vedat Akta
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2011 |
| Cilt / Sayı / Sayfa | 67 / 8 / – | DOI | 10.1107/S1600536811026535 |
| Makale Linki | https://doi.org/10.1107/s1600536811026535 | ||
| Özet |
| In the crystal structure of the polymeric title compound, {[Pb(C 9H 9O 2) 2(C 6H 6N 2O)]·H 2O} n , the six-coordinate Pb II ion is chelated by two 4-ethyl-benzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxyl-ate groups of the PEB ions are twisted away from the attached benzene rings by 4.0 (6) and 13.3 (5)°. The two benzene rings of the PEB ions bonded to the same metal ion are oriented at a dihedral angle of 87.4 (3)°. In the polymeric chain, the NA ligand is linked to one of the carboxyl-ate groups via N - H⋯O hydrogen bonding. In the crystal, adjacent polymeric chains inter-act via N - H⋯O and weak C - H⋯O hydrogen bonds; and the lattice water molecule links with the polymeric chains via N - H⋯O and O - H⋯O hydrogen bonding. π-π stacking between the benzene and the pyridine rings [centroid-centroid distance = 3.805 (5) Å] and weak C - H⋯π interactions are also observed in the crystal structure. |
| Anahtar Kelimeler |
| data-to-parameter ratio = 16.2 | mean σ(CC) = 0.013 Å | R factor = 0.043 | single-crystal X-ray study | T = 294 K | wR factor = 0.099 |
Science Direct
catena-Poly[[[bis(4-ethylbenzoato-κ2O,O')lead(II)]-μ-nicotinamide-κ2N1:O] monohydrate]
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 5 |
| SCOPUS | 5 |
| Google Scholar | 9 |