Diaquabis(4-bromobenzoato-κO)bis(nicotinamide-κN1)copper(II)
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Vijdan Ztürk
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Karabük Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2011 |
| Cilt / Sayı / Sayfa | 67 / 7 / 837–838 | DOI | 10.1107/S1600536811021696 |
| Makale Linki | https://journals.iucr.org/e/issues/2011/07/00/su2279/su2279.pdf | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| The asymmetric unit of the title mononuclear CuII complex,[Cu (C7H4BrO2) 2 (C6H6N2O) 2 (H2O) 2], contains one half-molecule, the CuII atom being located on an inversion center. The unit cell contains two nicotinamide (NA), two 4-bromobenzoate (PBB) ligands and two coordinated water molecules. The four O atoms in the equatorial plane around the CuII ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 22.17 (16), while the pyridine ring and the benzene ring are oriented at a dihedral angle of 82.80 (6). In the crystal, N—HÁÁÁO, O—HÁÁÁO and C—HÁÁÁO hydrogen bonds link the molecules into a threedimensional network. A weak C—HÁÁÁ interaction is also observed. |
| Anahtar Kelimeler |
Science Direct
Diaquabis(4-bromobenzoato-κO)bis(nicotinamide-κN1)copper(II)
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları |