Tetrakis[μ-4-(diethylamino)benzoato-κ2O:O′]bis[(N,N-diethylnicotinamide-κN1)cobalt(II)]

Hökelek, Tuncer; Saǧlam, Ertuǧrul Gazi; Tercan, Bariş; Aybirdid, Özgür; NECEFOĞLU, HACALİ

doi:10.1107/S160053681005004X

Tetrakis[μ-4-(diethylamino)benzoato-κ²O:O′]bis[(N,N-diethylnicotinamide-κN¹)cobalt(II)]

Yazarlar (5)

Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye

Ertuǧrul Gazi Saǧlam
Ankara Üniversitesi, Türkiye

Bariş Tercan
Karabük Üniversitesi, Türkiye

Özgür Aybirdid
Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online
Dergi ISSN	1600-5368
Makale Dili	İngilizce	Basım Tarihi	01-2011
Cilt / Sayı / Sayfa	67 / 1 / –	DOI	10.1107/S160053681005004X
Makale Linki	https://journals.iucr.org/e/issues/2011/01/00/xu5109/xu5109.pdf
UAK Araştırma Alanları	Fen Bilimleri ve Matematik

Özet

In the centrosymmetric binuclear title complex, [Co2(C 11H14-NO2)4(C10H 14N2O)2], the two Co^II cations [Co⋯Co = 2.6199 (5) Å ] are bridged by four 4-(diethylamino) benzoate (DEAB) anions. The four nearest O atoms around each Co^II ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of an N,N-diethylnicotinamide (DENA) ligand. The dihedral angle between the benzene ring and the carboxylate group is 7.06 (11)° in one of the independent DEAB ligands and 4.42 (9)° in the other. The benzene rings of the two independent DEAB ligands are oriented at a dihedral angle of 86.35 (8)°. The pyridine ring is oriented at dihedral angles of 31.43 (6) and 57.92 (7)° with respect to the two benzene rings. In the crystal, weak intermolecular C - H⋯ O interactions link the molecules into a three-dimensional network. Weak C - H⋯π interactions are also present in the crystal structure.

Anahtar Kelimeler

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları

Tetrakis[μ-4-(diethylamino)benzoato-κ²O:O′]bis[(N,N-diethylnicotinamide-κN¹)cobalt(II)]

Tetrakis[μ-4-(diethylamino)benzoato-κ2O:O′]bis[(N,N-diethylnicotinamide-κN1)cobalt(II)]

Paylaş

Tetrakis[μ-4-(diethylamino)benzoato-κ²O:O′]bis[(N,N-diethylnicotinamide-κN¹)cobalt(II)]