Tetrakis[μ-4-(diethylamino)benzoato-κ2O:O′]bis[(N,N-diethylnicotinamide-κN1)cobalt(II)]
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Ertuǧrul Gazi Saǧlam
Ankara Üniversitesi, Türkiye
Bariş Tercan
Karabük Üniversitesi, Türkiye
Özgür Aybirdid
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2011 |
| Cilt / Sayı / Sayfa | 67 / 1 / – | DOI | 10.1107/S160053681005004X |
| Makale Linki | https://journals.iucr.org/e/issues/2011/01/00/xu5109/xu5109.pdf | ||
| Özet |
| In the centrosymmetric binuclear title complex, [Co2(C 11H14-NO2)4(C10H 14N2O)2], the two CoII cations [Co⋯Co = 2.6199 (5) Å ] are bridged by four 4-(diethylamino) benzoate (DEAB) anions. The four nearest O atoms around each CoII ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of an N,N-diethylnicotinamide (DENA) ligand. The dihedral angle between the benzene ring and the carboxylate group is 7.06 (11)° in one of the independent DEAB ligands and 4.42 (9)° in the other. The benzene rings of the two independent DEAB ligands are oriented at a dihedral angle of 86.35 (8)°. The pyridine ring is oriented at dihedral angles of 31.43 (6) and 57.92 (7)° with respect to the two benzene rings. In the crystal, weak intermolecular C - H⋯ O interactions link the molecules into a three-dimensional network. Weak C - H⋯π interactions are also present in the crystal structure. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 8 |
| SCOPUS | 8 |
| Google Scholar | 15 |
| ResearchGate | 7 |