| Yazarlar |
Tuncer Hokelek
|
|
Ertugrul Gazi Saglam
|
|
Baris Tercan
|
|
Ozgur Aybirdi
|
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi |
| Özet |
| In the centrosymmetric binuclear title complex, [Co2(C 11H14-NO2)4(C10H 14N2O)2], the two CoII cations [Co⋯Co = 2.6199 (5) Å ] are bridged by four 4-(diethylamino) benzoate (DEAB) anions. The four nearest O atoms around each CoII ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of an N,N-diethylnicotinamide (DENA) ligand. The dihedral angle between the benzene ring and the carboxylate group is 7.06 (11)° in one of the independent DEAB ligands and 4.42 (9)° in the other. The benzene rings of the two independent DEAB ligands are oriented at a dihedral angle of 86.35 (8)°. The pyridine ring is oriented at dihedral angles of 31.43 (6) and 57.92 (7)° with respect to the two benzene rings. In the crystal, weak intermolecular C - H⋯ O interactions link the molecules into a three-dimensional network. Weak C - H⋯π interactions are also present in the crystal structure. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2011 |
| Cilt No | 67 |
| Sayı | 1 |
| Doi Numarası | 10.1107/S160053681005004X |
| Atıf Sayıları | |
| WoS | 7 |
| SCOPUS | 7 |
| Google Scholar | 18 |
| ResearchGate | 7 |
