| Yazarlar (5) |
|
Hacettepe Üniversitesi, Türkiye |
|
Ankara Üniversitesi, Türkiye |
|
Karabük Üniversitesi, Türkiye |
|
Kafkas Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
| Özet |
| In the dinuclear centrosymmetric CdII compound, [Cd 2(C8H8NO2)4(C 6H6N2O)2(H2O) 2], the metal atom is chelated by two carboxyl-ate groups from 4-(methyl-amino)-benzoate (PMAB) anions, and coordinated by one nicotinamide and one water molecule; a carboxyl-ate O atom from the adjacent PMAB anion bridges to the Cd atom, completing the irregular seven-coordination geometry. In the crystal, inter-molecular O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π contacts between the pyridine rings [centroid-centroid distance = 3.965 (1) Å] may further stabilize the structure. A weak C - H⋯π inter-action also occurs. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayınlanan tam makale |
| Dergi Adı |
|
| Dergi ISSN | 1600-5368 |
| Makale Dili | İngilizce |
| Basım Tarihi | 12-2010 |
| Cilt No | 66 |
| Sayı | 12 |
| Doi Numarası | 10.1107/S1600536810046258 |