Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}

Hökelek, Tuncer; Saǧlam, Ertuǧrul Gazi; Tercan, Bariş; Aybirdi, Özgür; NECEFOĞLU, HACALİ

doi:10.1107/S1600536810046258

Bis[μ-4-(methylamino)benzoato]-κ³O,O′:O;κ³O:O,O′-bis{aqua[4-(methylamino)benzoato-κ²O,O′](nicotinamide-κN)cadmium(II)}

Yazarlar (5)

Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye

Ertuǧrul Gazi Saǧlam
Ankara Üniversitesi, Türkiye

Bariş Tercan
Karabük Üniversitesi, Türkiye

Özgür Aybirdi
Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online
Dergi ISSN	1600-5368
Makale Dili	İngilizce	Basım Tarihi	12-2010
Cilt / Sayı / Sayfa	66 / 12 / –	DOI	10.1107/S1600536810046258
Makale Linki	https://doi.org/10.1107/s1600536810046258

Özet

In the dinuclear centrosymmetric CdII compound, [Cd 2(C8H8NO2)4(C 6H6N2O)2(H2O) 2], the metal atom is chelated by two carboxyl-ate groups from 4-(methyl-amino)-benzoate (PMAB) anions, and coordinated by one nicotinamide and one water molecule; a carboxyl-ate O atom from the adjacent PMAB anion bridges to the Cd atom, completing the irregular seven-coordination geometry. In the crystal, inter-molecular O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π contacts between the pyridine rings [centroid-centroid distance = 3.965 (1) Å] may further stabilize the structure. A weak C - H⋯π inter-action also occurs.

Anahtar Kelimeler

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
WoS	4
SCOPUS	5
ResearchGate	5

Bis[μ-4-(methylamino)benzoato]-κ³O,O′:O;κ³O:O,O′-bis{aqua[4-(methylamino)benzoato-κ²O,O′](nicotinamide-κN)cadmium(II)}

Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}

Paylaş

Bis[μ-4-(methylamino)benzoato]-κ³O,O′:O;κ³O:O,O′-bis{aqua[4-(methylamino)benzoato-κ²O,O′](nicotinamide-κN)cadmium(II)}