Yazarlar |
Tuncer Hokelek
|
Ertugrul Gazi Saglam
|
Baris Tercan
|
Ozgur Aybirdi
|
Hacali NECEFOĞLU
Kafkas Üniversitesi |
Özet |
In the dinuclear centrosymmetric CdII compound, [Cd 2(C8H8NO2)4(C 6H6N2O)2(H2O) 2], the metal atom is chelated by two carboxyl-ate groups from 4-(methyl-amino)-benzoate (PMAB) anions, and coordinated by one nicotinamide and one water molecule; a carboxyl-ate O atom from the adjacent PMAB anion bridges to the Cd atom, completing the irregular seven-coordination geometry. In the crystal, inter-molecular O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π contacts between the pyridine rings [centroid-centroid distance = 3.965 (1) Å] may further stabilize the structure. A weak C - H⋯π inter-action also occurs. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
Dergi ISSN | 1600-5368 |
Makale Dili | İngilizce |
Basım Tarihi | 12-2010 |
Cilt No | 66 |
Sayı | 12 |
Doi Numarası | 10.1107/S1600536810046258 |