Bis(4-methoxybenzoato)-κ2O,O′;κO-bis(nicotinamide-κN1)zinc(II)

Hökelek, Tuncer; Saka, Güner; Tercan, Bar; Tenlik, Erdinç; NECEFOĞLU, HACALİ

doi:10.1107/S1600536810032885

Bis(4-methoxybenzoato)-κ²O,O′;κO-bis(nicotinamide-κN¹)zinc(II)

Yazarlar (5)

Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye

Güner Saka Hitit University, Türkiye

Bar Tercan
Karabük Üniversitesi, Türkiye

Erdinç Tenlik Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online
Dergi ISSN	1600-5368
Makale Dili	İngilizce	Basım Tarihi	09-2010
Cilt / Sayı / Sayfa	66 / 9 / –	DOI	10.1107/S1600536810032885
Makale Linki	https://doi.org/10.1107/s1600536810032885

Özet

The asymmetric unit of the title complex, [Zn(C8H 7O3)2(C6H6N 2O)2], contains three crystallographically independent molecules with similar configurations. The Zn^II cation is coordinated by two N atoms of two nicotinamide ligands and three O atoms from two 4-methoxybenzoate anions in a distorted trigonalbipyramidal geometry. In each independent molecule, one Zn-O bond distance [2.5181 (12), 2.5931 (12) and 2.4085 (12) Å for the three molecules] is significantly longer than the other two. In the crystal structure, extensive N-H⋯O and C-H⋯O hydrogen bonding links the molecules into a three-dimensional network. π-π contacts between the pyridine rings and between the pyridine and benzene rings [centroid-centroid distances = 3.7655 (9) and 3.8453 (10) Å, respectively] further stabilize the crystal structure.

Anahtar Kelimeler

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Google Scholar	4

Bis(4-methoxybenzoato)-κ²O,O′;κO-bis(nicotinamide-κN¹)zinc(II)

Bis(4-methoxybenzoato)-κ2O,O′;κO-bis(nicotinamide-κN1)zinc(II)

Paylaş

Bis(4-methoxybenzoato)-κ²O,O′;κO-bis(nicotinamide-κN¹)zinc(II)