| Yazarlar |
Tuncer Hoekelek
|
|
Guener Saka
|
|
Baris Tercan
|
|
Erdinc Tenlik
|
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi |
| Özet |
| The asymmetric unit of the title complex, [Zn(C8H 7O3)2(C6H6N 2O)2], contains three crystallographically independent molecules with similar configurations. The ZnII cation is coordinated by two N atoms of two nicotinamide ligands and three O atoms from two 4-methoxybenzoate anions in a distorted trigonalbipyramidal geometry. In each independent molecule, one Zn-O bond distance [2.5181 (12), 2.5931 (12) and 2.4085 (12) Å for the three molecules] is significantly longer than the other two. In the crystal structure, extensive N-H⋯O and C-H⋯O hydrogen bonding links the molecules into a three-dimensional network. π-π contacts between the pyridine rings and between the pyridine and benzene rings [centroid-centroid distances = 3.7655 (9) and 3.8453 (10) Å, respectively] further stabilize the crystal structure. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 1600-5368 |
| Makale Dili | İngilizce |
| Basım Tarihi | 90-2010 |
| Cilt No | 66 |
| Doi Numarası | 10.1107/S1600536810032885 |
| Atıf Sayıları | |
| WoS | 7 |
| SCOPUS | 7 |
