Bis(μ-4-methylbenzoato-κ2O:O′)bis[aqua(4-methylbenzoato-κ2O,O′)zinc(II)]-bis(μ-4-methylbenzoato-κ2O:O′)bis[(4-methylbenzoato-κO)(nicotinamide-κN)zinc(II)]-water (1/1/2)

Hokelek, Tuncer; Ermis, Emel; Tercan, Baris; ÇİMEN, EFDAL; NECEFOĞLU, HACALİ

doi:10.1107/S1600536810022476

Bis(μ-4-methylbenzoato-κ²O:O′)bis[aqua(4-methylbenzoato-κ²O,O′)zinc(II)]-bis(μ-4-methylbenzoato-κ²O:O′)bis[(4-methylbenzoato-κO)(nicotinamide-κN)zinc(II)]-water (1/1/2)

Yazarlar (5)

Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye

Prof. Dr. Emel Ermis Anadolu Üniversitesi, Türkiye

Baris Tercan
Karabük Üniversitesi, Türkiye

Dr. Öğr. Üyesi Efdal ÇİMEN Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online (Q4)
Dergi ISSN	1600-5368 Dergi Bilgileri (2010)
Makale Dili	İngilizce	Basım Tarihi	07-2010
Cilt / Sayı / Sayfa	66 / 7 / –	DOI	10.1107/S1600536810022476
Makale Linki	https://journals.iucr.org/e/issues/2010/07/00/xu2762/xu2762.pdf
UAK Araştırma Alanları	Fen Bilimleri ve Matematik

Özet

The crystal structure of the title compound, [Zn2(C8H7O2)4(H2O)2]·[Zn2(C8H7O2)4(C6H6N2O)2]·2H2O, consists of two kinds of dinuclear ZnII complexes (complex A and complex B) and uncoordinated water molecules. In complex A, [Zn2(C8H7O2)4(H2O)2], each Zn cation is chelated by a 4-methylbenzoate (PMB) anion and coordinated by a water molecule, and is further bridged by two PMB anions in a trigonal-bipyramidal geometry. In complex B, [Zn2(C8H7O2)4(C6H6N2O)2], each ZnII cation is coordinated by a monodentate PMB anion and one nicotinamide (NA) ligand, and is further bridged by two PMB anions in a tetrahedral geometry. Weak intra-molecular π–π stacking between adjacent benzene rings is observed in complex B, the centroid–centroid distance being 3.710 (2) Å. Extensive O—H⋯O and N—H⋯O hydrogen bonding and weak C—H⋯O hydrogen bonding is present in the crystal structure …

Anahtar Kelimeler

Science Direct

Atıf Sayıları
Web of Science	2
Scopus	2
Google Scholar	3

Bis(μ-4-methylbenzoato-κ²O:O′)bis[aqua(4-methylbenzoato-κ²O,O′)zinc(II)]-bis(μ-4-methylbenzoato-κ²O:O′)bis[(4-methylbenzoato-κO)(nicotinamide-κN)zinc(II)]-water (1/1/2)

Dergi Adı	ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Kısa Adı	ACTA CRYSTALLOGR E
Yayıncı	WILEY-BLACKWELL
Açık Erişim	Evet
ISSN	1600-5368
E-ISSN	2056-9890
Wos Quartile	Q4
Scopus Quartile	Q3
Tarandığı Indeksler	SCIE , Scopus
WoS Kategoriler	CRYSTALLOGRAPHY
Scopus Kategoriler	CHEMISTRY (MISCELLANEOUS) \| MATERIALS SCIENCE (MISCELLANEOUS) \| CONDENSED MATTER PHYSICS

Bis(μ-4-methylbenzoato-κ2O:O′)bis[aqua(4-methylbenzoato-κ2O,O′)zinc(II)]-bis(μ-4-methylbenzoato-κ2O:O′)bis[(4-methylbenzoato-κO)(nicotinamide-κN)zinc(II)]-water (1/1/2)

Paylaş

Bis(μ-4-methylbenzoato-κ²O:O′)bis[aqua(4-methylbenzoato-κ²O,O′)zinc(II)]-bis(μ-4-methylbenzoato-κ²O:O′)bis[(4-methylbenzoato-κO)(nicotinamide-κN)zinc(II)]-water (1/1/2)