| Yazarlar (5) |
|
Hacettepe Üniversitesi, Türkiye |
|
Anadolu Üniversitesi, Türkiye |
|
Karabük Üniversitesi, Türkiye |
|
Kafkas Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
| Özet |
| In the title complex, [Co(C8H7O3) 2(C6H6N2O)(H2O) 2], the CoII atom is coordinated by three O atoms from two 4-methoxy-benzoate ligands, which act in different modes, viz. monodentate and bidentate, two water molecules and one N atom of the isonicotinamide ligand in a distorted octa-hedral geometry. The monodentate-coordinated carboxylate group is involved in an intra-molecular O-H⋯O hydrogen bond with the coordinated water molecule. In the crystal structure, inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the molecules into layers parallel to the ab plane. The crystal packing is further stabilized by weak C-H⋯O hydrogen bonds and π-π inter-actions indicated by the short distance of 3.6181 (8) Å between the centroids of the benzene and pyridine rings of neighbouring molecules. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayınlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi |
| Makale Dili | İngilizce |
| Basım Tarihi | 07-2010 |
| Cilt No | 66 |
| Sayı | 7 |
| Doi Numarası | 10.1107/S160053681002194X |