Di-μ-nicotinamide-κ2O:N1;κ2N1:O-bis[aquabis(4-methoxybenzoato-κO)copper(II)]

Hokelek, Tuncer; Suzen, Yasemin; Tercan, Baris; Tenlik, Erdinc; NECEFOĞLU, HACALİ

doi:10.1107/S1600536810022415

Di-μ-nicotinamide-κ²O:N¹;κ²N¹:O-bis[aquabis(4-methoxybenzoato-κO)copper(II)]

Yazarlar (5)

Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye

Yasemin Suzen
Anadolu Üniversitesi, Türkiye

Baris Tercan
Karabük Üniversitesi, Türkiye

Erdinc Tenlik
Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online
Dergi ISSN	1600-5368
Makale Dili	İngilizce	Basım Tarihi	07-2010
Cilt / Sayı / Sayfa	66 / 7 / –	DOI	10.1107/S1600536810022415
Makale Linki	https://journals.iucr.org/e/issues/2010/07/00/cv2731/cv2731.pdf

Özet

The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu2(C8H7O3)4(C 6H6N2O)2(H2O) 2], contains one half of the complex molecule. Each Cu^II atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, two O atoms from two 4-methoxy-benzoate ligands, and one water molecule, forming a distorted square-pyramidal geometry. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the molecules into layers parallel to ( 01). π-π inter-actions, indicated by short inter-molecular distances of 3.801 (1) Å between the centroids of the benzene rings and 3.653 (1) Å between the centroids of the pyridine rings, further stabilize the structure.

Anahtar Kelimeler

Science Direct

Atıf Sayıları
Web of Science	7

Di-μ-nicotinamide-κ²O:N¹;κ²N¹:O-bis[aquabis(4-methoxybenzoato-κO)copper(II)]

Di-μ-nicotinamide-κ2O:N1;κ2N1:O-bis[aquabis(4-methoxybenzoato-κO)copper(II)]

Paylaş

Di-μ-nicotinamide-κ²O:N¹;κ²N¹:O-bis[aquabis(4-methoxybenzoato-κO)copper(II)]