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Di-μ-nicotinamide-κ2O:N12N1:O-bis[aquabis(4-methoxybenzoato-κO)copper(II)]       
Yazarlar (5)
Tuncer Hokelek
Yasemin Suzen
Baris Tercan
Erdinc Tenlik
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi
Devamını Göster
Özet
The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu2(C8H7O3)4(C 6H6N2O)2(H2O) 2], contains one half of the complex molecule. Each CuII atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, two O atoms from two 4-methoxy-benzoate ligands, and one water molecule, forming a distorted square-pyramidal geometry. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the molecules into layers parallel to ( 01). π-π inter-actions, indicated by short inter-molecular distances of 3.801 (1) Å between the centroids of the benzene rings and 3.653 (1) Å between the centroids of the pyridine rings, further stabilize the structure.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Dergi ISSN 1600-5368
Makale Dili İngilizce
Basım Tarihi 07-2010
Cilt No 66
Sayı 7
Doi Numarası 10.1107/S1600536810022415