img
Di-μ-nicotinamide-κ2O:N12N1:O-bis[aquabis(4-methoxybenzoato-κO)copper(II)]       
Yazarlar
Tuncer Hokelek
Yasemin Suzen
Baris Tercan
Erdinc Tenlik
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi
Özet
The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu2(C8H7O3)4(C 6H6N2O)2(H2O) 2], contains one half of the complex molecule. Each CuII atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, two O atoms from two 4-methoxy-benzoate ligands, and one water molecule, forming a distorted square-pyramidal geometry. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the molecules into layers parallel to ( 01). π-π inter-actions, indicated by short inter-molecular distances of 3.801 (1) Å between the centroids of the benzene rings and 3.653 (1) Å between the centroids of the pyridine rings, further stabilize the structure.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Dergi ISSN 1600-5368
Makale Dili İngilizce
Basım Tarihi 07-2010
Cilt No 66
Sayı 7
Doi Numarası 10.1107/S1600536810022415