catena-Poly[[(4-methylbenzoato-κO)manganese(II)]-μ-aqua-bis(μ-4-methylbenzoato-κ2O:O′)[(4-methylbenzoato-κO)manganese(II)]-bis(μ-N,N-diethylnicotinamide)-κ2N3:O;O:N3]

Hokelek, Tuncer; Dal, Hakan; Tercan, Baris; ÇİMEN, EFDAL; NECEFOĞLU, HACALİ

doi:10.1107/S1600536810020076

catena-Poly[[(4-methylbenzoato-κO)manganese(II)]-μ-aqua-bis(μ-4-methylbenzoato-κ²O:O′)[(4-methylbenzoato-κO)manganese(II)]-bis(μ-N,N-diethylnicotinamide)-κ²N³:O;O:N³]

Yazarlar (5)

Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye

Prof. Dr. Hakan Dal Anadolu Üniversitesi, Türkiye

Baris Tercan
Karabük Üniversitesi, Türkiye

Dr. Öğr. Üyesi Efdal ÇİMEN Kafkas Üniversitesi, Türkiye

Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Acta Crystallographica Section E Structure Reports Online
Dergi ISSN	1600-5368
Makale Dili	İngilizce	Basım Tarihi	07-2010
Cilt / Sayı / Sayfa	66 / 7 / –	DOI	10.1107/S1600536810020076
Makale Linki	https://doi.org/10.1107/s1600536810020076
UAK Araştırma Alanları	Fen Bilimleri ve Matematik

Özet

The asymmetric unit of the title complex, [Mn2(C 8H7O2)4(C10H 14N2O)2(H2O)]n , contains two crystallographically independent units. In each one, the Mn^II ions are bridged by two 4-methyl-benzoate (PMB) ligands and one water molecule. In the crystal structure, each Mn^II ion is coordinated by three PMB ligands, one water molecule and two symmetry-related N,N-diethyl-nicotinamide (DENA) ligands. Symmetry-related Mn^II ions are bridged by the N and O atoms of symmetry-related DENA ligands, forming polymeric chains parallel to [100]. The coord-ination environmnts for the Mn^II ions are slightly distorted octa-hedral. Intra-molecular O-H⋯O hydrogen bonds link bridging water molecules to the carboxylate O atoms of a neigh-boring polymeric chain. In the crystal structure, π-π contacts between benzene rings [centroid-centroid distance = 3.562 (1) Å] and weak C-H⋯π inter-actions are also observed.

Anahtar Kelimeler

Science Direct

Atıf Sayıları

catena-Poly[[(4-methylbenzoato-κO)manganese(II)]-μ-aqua-bis(μ-4-methylbenzoato-κ²O:O′)[(4-methylbenzoato-κO)manganese(II)]-bis(μ-N,N-diethylnicotinamide)-κ²N³:O;O:N³]

catena-Poly[[(4-methylbenzoato-κO)manganese(II)]-μ-aqua-bis(μ-4-methylbenzoato-κ2O:O′)[(4-methylbenzoato-κO)manganese(II)]-bis(μ-N,N-diethylnicotinamide)-κ2N3:O;O:N3]

Paylaş

catena-Poly[[(4-methylbenzoato-κO)manganese(II)]-μ-aqua-bis(μ-4-methylbenzoato-κ²O:O′)[(4-methylbenzoato-κO)manganese(II)]-bis(μ-N,N-diethylnicotinamide)-κ²N³:O;O:N³]