| Yazarlar |
Tuncer Hokelek
|
|
Hakan Dal
|
|
Baris Tercan
|
|
Efdal Cimen
|
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi |
| Özet |
| The asymmetric unit of the title complex, [Mn2(C 8H7O2)4(C10H 14N2O)2(H2O)]n , contains two crystallographically independent units. In each one, the MnII ions are bridged by two 4-methyl-benzoate (PMB) ligands and one water molecule. In the crystal structure, each MnII ion is coordinated by three PMB ligands, one water molecule and two symmetry-related N,N-diethyl-nicotinamide (DENA) ligands. Symmetry-related MnII ions are bridged by the N and O atoms of symmetry-related DENA ligands, forming polymeric chains parallel to [100]. The coord-ination environmnts for the MnII ions are slightly distorted octa-hedral. Intra-molecular O-H⋯O hydrogen bonds link bridging water molecules to the carboxylate O atoms of a neigh-boring polymeric chain. In the crystal structure, π-π contacts between benzene rings [centroid-centroid distance = 3.562 (1) Å] and weak C-H⋯π inter-actions are also observed. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 1600-5368 |
| Makale Dili | İngilizce |
| Basım Tarihi | 70-2010 |
| Cilt No | 66 |
| Doi Numarası | 10.1107/S1600536810020076 |
