| Yazarlar |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi |
Efdal Cimen
|
|
Baris Tercan
|
|
Hakan Dal
|
|
Tuncer Hokelek
|
| Özet |
| In the mononuclear title complex, [Mn(C8H7O 2)2(C6H6N2O) 2(H2O)2], the MnII ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methylbenzoate anion, one nicotinamide (NA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the MnII ion form a slightly distorted squareplanar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 9.01 (7)̊, while the pyridine and benzene rings are oriented at a dihedral angle of 42.44 (5)̊. In the crystal structure, intermolecular O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds, and O - H⋯π and C - H⋯π interactions link the mol-ecules into a twodimensional network parallel to (001). © 2010. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Makale Dili | İngilizce |
| Basım Tarihi | 05-2010 |
| Cilt No | 66 |
| Sayı | 5 |
| Doi Numarası | 10.1107/S1600536810011815 |
| Atıf Sayıları |
