Tetrakis(μ-4-methylbenzoato-κ2O:O′)bis[(N,N-diethylnicotinamide-κN1)zinc(II)\]
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Efdal Imen
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Bariş Tercan
Karabük Üniversitesi, Türkiye
Karabük Üniversitesi, Türkiye
Hakan Dal Anadolu Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2010 |
| Cilt / Sayı / Sayfa | 66 / 4 / – | DOI | 10.1107/S1600536810011517 |
| Makale Linki | https://journals.iucr.org/e/issues/2010/04/00/xu2740/xu2740.pdf | ||
| Özet |
| In the centrosymmetric binuclear title complex, [Zn2(C 8H7O2)4(C10H 14N2O)2], the Zn atoms [Zn⋯Zn' = 2.9494 (3) Å] are bridged by four 4-methyl-benzoate (PMB) anions. The four nearest O atoms around each ZnII ion form a distorted square-planar arrangement, the octahedral coordin-ation being completed by the pyridine N atom of the N,N-diethyl-nicotinamide (DENA) ligand. Each ZnII ion is displaced by 0.3530 (1) Å from the plane of the four O atoms. The dihedral angles between carboxyl-ate groups and their adjacent benzene rings are 5.88 (10) and 11.89 (9)°, while the benzene rings are oriented at a dihedral angle of 75.19 (4)°. The pyridine ring is oriented at dihedral angles of 38.28 (4) and 49.17 (4)° with respect to the benzene rings. In the crystal structure, weak inter-molecular C - H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. π-π contacts between parallel benzene rings [centroid-centroid distance = 3.8388 (8) Å] and between parallel pyridine rings [centroid-centroid distance = 3.4855 (7) Å] may further stabilize the crystal structure. |
| Anahtar Kelimeler |
Science Direct
Tetrakis(μ-4-methylbenzoato-κ2O:O′)bis[(N,N-diethylnicotinamide-κN1)zinc(II)\]
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 3 |
| SCOPUS | 4 |
| Google Scholar | 13 |
| ResearchGate | 4 |