| Makale Türü |
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2010 |
| Cilt / Sayı / Sayfa | 66 / 4 / – | DOI | 10.1107/S1600536810010706 |
| Makale Linki | https://doi.org/10.1107/s1600536810010706 | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
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| Özet |
| The asymmetric unit of the title CoII complex, [Co(C8H8NO2)2(C6H6N2O)2(H2O)2], contains two half complex molecules with similar structures. The CoII atoms are each located on an inversion center and each is coordinated by two 4-methylaminobenzoate (PMAB), two nicotinamide (NA) ligands and two water molecules in a distorted octahedral coordination. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 3.0 (3) and 2.54 (19)°, while the pyridine and benzene rings are oriented at dihedral angles of 67.40 (8) and 66.25 (8)°. In the crystal structure, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a supramolecular structure. |
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