| Yazarlar |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi |
Efdal Cimen
|
|
Baris Tercan
|
|
Yasemin Suzen
|
|
Tuncer Hokelek
|
| Özet |
| In the crystal structure of the title compound, [Cd(C8H 7O2)2(C6H6N 2O)2(H2O)]·H2O, the Cd II cation is coordinated by two 4-methyl-benzoate (PMB) anions, two isonicotinamide (INA) ligands and one water mol-ecule in a distorted octa-hedral CdN2O4 geometry. One of PMB ions acts as a bidentate ligand while the other and the two INA are monodentate ligands. An O - H⋯O hydrogen bond links the uncoordinated water mol-ecule to the carboxyl groups of the complex. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 10.28 (11) and 21.24 (9)°, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 6.90 (4) and 88.64 (4)°, respectively. In the crystal structure, O - H⋯O and N - H⋯O hydrogen bonds link the mol-ecules into a supra-molecular structure. A π-π contact between the benzene rings [centroid-centroid distance = 3.911 (1) Å] may further stabilize the crystal structure. Weak C - H⋯π inter-actions involving the pyridine rings also occur in the crystal structure. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 |
| Makale Dili | İngilizce |
| Basım Tarihi | 04-2010 |
| Cilt No | 66 |
| Sayı | 4 |
| Doi Numarası | 10.1107/S1600536810008366 |
| Atıf Sayıları | |
| WoS | 1 |
| SCOPUS | 1 |
