Aquabis(isonicotinamide-κN1)bis(4-methylbenzoato)-κO;κ2O,O′-cadmium(II) monohydrate
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Dr. Öğr. Üyesi Efdal ÇİMEN Kafkas Üniversitesi, Türkiye
Baris Tercan
Karabük Üniversitesi, Türkiye
Karabük Üniversitesi, Türkiye
Yasemin Suzen
Anadolu Üniversitesi, Türkiye
Anadolu Üniversitesi, Türkiye
Tuncer Hokelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2010 |
| Cilt / Sayı / Sayfa | 66 / 4 / – | DOI | 10.1107/S1600536810008366 |
| Makale Linki | https://journals.iucr.org/e/issues/2010/04/00/xu2732/xu2732.pdf | ||
| Özet |
| In the crystal structure of the title compound, [Cd(C8H 7O2)2(C6H6N 2O)2(H2O)]·H2O, the Cd II cation is coordinated by two 4-methyl-benzoate (PMB) anions, two isonicotinamide (INA) ligands and one water mol-ecule in a distorted octa-hedral CdN2O4 geometry. One of PMB ions acts as a bidentate ligand while the other and the two INA are monodentate ligands. An O - H⋯O hydrogen bond links the uncoordinated water mol-ecule to the carboxyl groups of the complex. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 10.28 (11) and 21.24 (9)°, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 6.90 (4) and 88.64 (4)°, respectively. In the crystal structure, O - H⋯O and N - H⋯O hydrogen bonds link the mol-ecules into a supra-molecular structure. A π-π contact between the benzene rings [centroid-centroid distance = 3.911 (1) Å] may further stabilize the crystal structure. Weak C - H⋯π inter-actions involving the pyridine rings also occur in the crystal structure. |
| Anahtar Kelimeler |
Science Direct
Aquabis(isonicotinamide-κN1)bis(4-methylbenzoato)-κO;κ2O,O′-cadmium(II) monohydrate
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 1 |
| SCOPUS | 1 |