| Yazarlar |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi |
Efdal Cimen
|
|
Baris Tercan
|
|
Emel Ermis
|
|
Tuncer Hokelek
|
| Özet |
| The title NiII complex, [Ni(C8H7O 2)2(C6H6N2O) 2(H2O)2], is centrosymmetric with the Ni atom located on an inversion center. The mol-ecule contains two 4-methyl-benzoate (PMB) and two nicotinamide (NA) ligands and two coordinated water mol-ecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 26.15 (10)°, while the pyridine and benzene rings are oriented at a dihedral angle of 87.81 (4)°. In the crystal structure, inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. The π-π contact between the benzene rings [centroid-centroid distance = 3.896 (1) Å] may further stabilize the crystal structure. A weak C - H⋯π inter-action involving the pyridine ring also occurs. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | ESCI dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 1600-5368 |
| Makale Dili | İngilizce |
| Basım Tarihi | 40-2010 |
| Cilt No | 66 |
| Doi Numarası | 10.1107/S1600536810007385 |
| Atıf Sayıları | |
| WoS | 7 |
| SCOPUS | 8 |
